授業の目的 【日本語】
Goals of the Course(JPN) | | |
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授業の目的 【英語】
Goals of the Course | | The purpose of this course is to provide students with a comprehensive understanding of classical thermodynamics and its applications to chemical and physical systems.
Students will learn the fundamental laws of thermodynamics and develop the ability to:
- Explain the concepts of internal energy, enthalpy, entropy, and free energy.
- Apply thermodynamic principles to gases, phase transitions, and chemical reactions.
- Interpret phase diagrams and equilibrium conditions in multi-component systems.
- Understand the thermodynamics of solutions, colligative properties, and their relevance to real systems. |
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到達目標 【日本語】
Objectives of the Course(JPN)) | | |
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到達目標 【英語】
Objectives of the Course | | By taking this course, students will be able to:
- Acquire knowledge of the fundamental laws of thermodynamics and their applications to chemical and physical systems.
- Develop the ability to explain the relationships among internal energy, enthalpy, entropy, free energy, and chemical reactions.
- Apply thermodynamic concepts to gases, phase transitions, chemical equilibria, and solutions.
- Interpret and analyze phase diagrams and multi-component systems.
- Strengthen their scientific reasoning skills and the ability to connect theoretical principles with real-world phenomena. |
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授業の内容や構成
Course Content / Plan | | 1. Properties of Gases and the Ideal Gas Law
Introduction to the properties of gases, the equation of state of an ideal gas, and the kinetic theory of gases.
2. Real Gases and Liquefaction
Deviation from ideal behavior, equations of state for real gases, and the thermodynamics of liquefaction.
3. The First Law of Thermodynamics
Definition of internal energy, heat, and work (mechanical work, PV work).
4. Heat and the Second Law of Thermodynamics
The second law, entropy, and the principles of heat engines including the Carnot cycle.
5. Equilibrium Conditions and Entropy
Conditions for thermodynamic equilibrium, entropy as a state function, and entropy changes.
6. Free Energy and State Probability
State probability, relative population, and free energy derived from statistical considerations.
7. Thermodynamic Functions and Chemical Potential
Legendre transformations, chemical potential, Gibbs–Duhem relation, and chemical potential in mixtures.
8. Chemical Reactions and Equilibrium
Le Chatelier’s principle, chemical equilibrium, and various forms of equilibrium constants.
9. Phase Transitions and Phase Diagrams I
Basic concepts of phase transitions, thermodynamics of phase transitions, and the Clausius–Clapeyron equation.
10. Phase Transitions and Phase Diagrams II
Classification of phase transitions (Ehrenfest), measurement methods, and the phase rule.
11. Thermodynamics of Solutions I
Partial molar quantities, concentration scales, Raoult’s law, and Henry’s law.
12. Thermodynamics of Solutions II
Real solutions, activity, and Gibbs free energy of mixing in non-ideal systems.
13. Chemistry of Solutions and Multi-Component Systems
pX and TX diagrams, partially miscible liquids, solid–liquid phase diagrams, and ternary systems.
14. Colligative Properties of Solutions
Freezing-point depression, vapor-pressure lowering, and osmotic pressure.
15. Summary and Applications
Comprehensive review of thermodynamic principles, with applications to chemical and biological systems. |
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履修条件
Course Prerequisites | | | There are no particular prerequisites or conditions required for enrollment in this course. |
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関連する科目
Related Courses | | | Basic courses in physics, chemistry, and mathematics (including calculus and general chemistry. |
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「履修取り下げ届」提出の要・不要
Necessity / Unnecessity to submit "Course Withdrawal Request Form" | | | A Course Withdrawal Form is required. |
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履修取り下げの条件等
Conditions for Course Withdrawal | | | No specific conditions apply. |
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成績評価の方法と基準
Course Evaluation Method and Criteria | | Quizzes: 80%, Class Attitude: 20%
There will be no final exam. Grades will be assigned on the S/A/B/C/F scale based on quizzes and class attitude. |
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不可(F)と欠席(W)の基準
Criteria for "Fail (F)" & "Absent (W)" grades | | - F : Assigned when the total score from quizzes and class attitude is less than 30% of the full score.
- W : Assigned when the number of quizzes submitted is less than 80% of the total. |
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参考書
Reference Book | | | Additional reference materials will be indicated as appropriate during the course. |
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教科書・テキスト
Textbook | | | Atkins’ Physical Chemistry, Oxford University Press. |
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課外学習等（授業時間外学習の指示）
Study Load(Self-directed Learning Outside Course Hours) | | | Students are required to review lecture materials and relevant textbook sections after each class. Approximately 2–3 hours of self-study per week are expected to ensure adequate understanding and exam readiness. |
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注意事項
Notice for Students | | |
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他学科聴講の可否
Propriety of Other department student's attendance | | |
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他学科聴講の条件
Conditions for Other department student's attendance | | |
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レベル
Level | | |
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キーワード
Keyword | | |
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履修の際のアドバイス
Advice | | |
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授業開講形態等
Lecture format, etc. | | | The course will be conducted primarily in face-to-face classes. In cases where the instructor is unable to teach in person (e.g., due to business trips), the class may be delivered in an on-demand format. |
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遠隔授業（オンデマンド型）で行う場合の追加措置
Additional measures for remote class (on-demand class) | | |
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